Insight into the Iron–Molybdenum Cofactor of Nitrogenase from ...

https://pubs.acs.org/doi/10.1021/jacs.6b00747

12 May 2016 ... In one direction, synthetic iron complexes have now been shown to bind N2, ... clusters would provide insight into the role of Mo in the FeMoco.

Insight into the FeMoco of nitrogenase from synthetic iron complexes ...

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5508211/

15 Jun 2016 ... Insight into the FeMoco of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands. Ilija Čorić and Patrick L. Holland.

Insight into the Iron-Molybdenum Cofactor of Nitrogenase from ...

https://pubmed.ncbi.nlm.nih.gov/27171599/

15 Jun 2016 ... On the FeMoco, N2 binding is suggested to occur at one or more iron ... In one direction, synthetic iron complexes have now been shown to ...

Incorporating light atoms into synthetic analogues of FeMoco | PNAS

https://www.pnas.org/content/115/20/5054

15 May 2018 ... (2016) Insight into the iron-molybdenum cofactor of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands.

Insight into the FeMoco of nitrogenase from synthetic iron complexes ...

https://www.researchgate.net/publication/303028845_Insight_into_the_FeMoco_of_nitrogenase_from_synthetic_iron_complexes_with_sulfur_carbon_and_hydride_ligands

Download Citation | Insight into the FeMoco of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands | Nitrogenase enzymes are ...

Insight into the Iron-Molybdenum Cofactor of Nitrogenase from ...

https://europepmc.org/article/pmc/pmc5508211

Insight into the Iron-Molybdenum Cofactor of Nitrogenase from Synthetic Iron ... On the FeMoco, N2 binding is suggested to occur at one or more iron atoms, but the ... In one direction, synthetic iron complexes have now been shown to bind N2, ...

Nitrogenase and Nitrogen Activation | The Holland Group

https://holland.chem.yale.edu/research/nitrogenase-and-nitrogen-activation

In both cases, N2 reduction is proposed to take place on iron sites. ... Insight into the FeMoco of nitrogenase from synthetic iron complexes with sulfur, carbon, ...

Incorporating light atoms into synthetic analogues of FeMoco

http://www.pnas.org/content/pnas/115/20/5054.full.pdf

30 Apr 2018 ... metal clusters with topological similarity to the FeMoco ... 2 ˇCori c I, Holland PL ( 2016) Insight into the iron-molybdenum cofactor of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands. J Am.

Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster ...

https://www.nature.com/articles/s41557-019-0341-7

14 Oct 2019 ... Four-coordinate belt iron atoms in the FeMoco (Fig. ... Three-coordinate iron in a cluster may therefore provide insight into the properties that ... are adept at stabilizing low-coordinate metal sites in coordination complexes. ... to the all-Fe2 + cubane of the [4Fe-4S] iron protein in nitrogenase (average Fe–S ...

The influences of carbon donor ligands on biomimetic multi-iron ...

https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc03447a

1 (a) Structure of the resting state of FeMoco with Fe2 and Fe6 labeled for clarity. ... (c) Synthetic iron complexes featuring C-donors capable of N2 reduction to NH 4+; ... insights as structural or functional models of nitrogenase, but accessing ...

Nitrogen Reduction to Ammonia on a Biomimetic Mononuclear Iron ...

https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201704688

22 Nov 2017 ... As a result, model complexes have been developed to gain insight into these ... of the few synthetic mononuclear iron complexes known to be able to reduce ... and electrons in analogy to the FeMoco cluster of nitrogenase.

Insight into the Iron-Molybdenum Cofactor of Nitrogenase from ...

https://www.semanticscholar.org/paper/Insight-into-the-Iron-Molybdenum-Cofactor-of-from-%C4%8Cori%C4%87-Holland/1dabdc161f9ce3c91d7b9fd5a9d8671591165191

On the FeMoco, N2 binding is suggested to occur at one or more iron atoms, but ... In one direction, synthetic iron complexes have now been shown to bind N2, ...

Exploring the effects of multi-iron site cooperativity and second ...

https://grantome.com/grant/NIH/F31-GM116463-01

Nitrogenase is an enzyme that is able to cleave the seemingly inert NN triple ... of complexes to reduce N2 in will offer insight to the mechanism of nitrogenase. ... will be tested by synthesis of complexes that divide and simplify the FeMoco ...

Progress in Synthesizing Analogues of Nitrogenase Metalloclusters ...

https://www.mdpi.com/2073-4344/9/11/939/htm

Catalytic NH3 synthesis is an attractive and promising alternative approach. ... have taken inspiration from nitrogenase metal clusters and have focused their efforts on ... Based on the detailed insights into the nitrogenase reaction mechanism, ... and the FeMo-co by two different stable Fe-protein–MoFe-protein complexes as ...

Catalysts for Nitrogen Reduction to Ammonia

https://www.osti.gov/pages/servlets/purl/1481881

complex. Overall, the HBP accounts for ~1% of the world's yearly natural gas consumption and is responsible ... potential insights for selectivity in heterogeneous catalyst design. ... The synthesis of ammonia from dinitrogen by nitrogenase follows ... iron atoms in the FeMo-co (iron atoms labeled one, three and seven in Fig.

Alternative Strategies Toward Sustainable Ammonia Synthesis ...

https://link.springer.com/article/10.1007/s12209-020-00243-x

13 Mar 2020 ... Figure 1b illustrates the structure of FeMoco, which contains seven Fe atoms ... Although nitrogenase has long existed in nature, artificial N2 fixation was ... Holland further studied a synthetic complex with a sulfur-rich ... Čorić I, Holland PL (2016) Insight into the iron-molybdenum cofactor of nitrogenase from ...

Insight into the Iron-Molybdenum Cofactor of Nitrogenase from ...

https://docksci.com/insight-into-the-iron-molybdenum-cofactor-of-nitrogenase-from-synthetic-iron-com_5a0d2e55d64ab2c5e9d576f0.html

Insight into the FeMoco of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands Ilija Čorić and Patrick L. Holland* Department of ...

Biosynthesis of the Metalloclusters of Molybdenum Nitrogenase ...

https://mmbr.asm.org/content/75/4/664

The FeMoco is buried within the α-subunit of MoFe protein, 14 Å away from the ... spectroscopic insights into the biosynthesis of the two complex metal clusters of ... for synthesis of the iron-molybdenum cofactor of nitrogenase as homocitrate.

Biosynthesis of the Iron-Molybdenum Cofactor of Nitrogenase ...

https://www.annualreviews.org/doi/abs/10.1146/annurev.micro.62.081307.162737

13 Oct 2008 ... The iron-molybdenum cofactor (FeMo-co), located at the active site of the molybdenum nitrogenase, is one of the most complex metal cofactors known to date. ... has been made to purify the proteins involved in FeMo-co synthesis ... This effort is starting to provide insights into the structures of the FeMo-co ...

New insights into the evolutionary history of biological ... - Frontiers

https://www.frontiersin.org/articles/10.3389/fmicb.2013.00201/full

5 Aug 2013 ... Nitrogenase, which catalyzes the ATP-dependent reduction of dinitrogen (N2) ... Concatenations of paralogous proteins involved in the synthesis of ... the complex iron-molybdenum cofactor (FeMo-co) located at the active site ...

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